- English
- فارسی
paper39
Authors
Kazem Karami, Mahboubeh Hosseini-Kharat, Corrado Rizzoli, Hossein Tavakol, Janusz Lipkowski
Publication date
2014/2/15
Journal
Journal of Organometallic Chemistry
Volume
752
Pages
152-160
Publisher
Elsevier
Description
Abstract The reactivity of the dinuclear cyclopalladated complexes derived from secondary
benzylamines,[Pd 2 {(C, N)–C 6 H 4 CH 2 NH (R)} 2 (μ-X) 2][X= Br, R= t-Bu (1a); X= Cl, R= t-
Bu (1b); X= Cl, R= Et (1c)] is reported. 1a reacted with dimethyl acetylenedicarboxylate
(DMAD) to yield the mono-inserted complex [Pd 2 {(C, N)–C (CO 2 Me) double bond; length
as m-dash
benzylamines,[Pd 2 {(C, N)–C 6 H 4 CH 2 NH (R)} 2 (μ-X) 2][X= Br, R= t-Bu (1a); X= Cl, R= t-
Bu (1b); X= Cl, R= Et (1c)] is reported. 1a reacted with dimethyl acetylenedicarboxylate
(DMAD) to yield the mono-inserted complex [Pd 2 {(C, N)–C (CO 2 Me) double bond; length
as m-dash