Leila Tabrizi, Hossein Chiniforoshan, Patrick McArdle, Hossein Tavakol, Behzad Rezaei, Mohammad Mohammadi Dehcheshmeh

2014/2/17

Polyhedron

69

84-89

Pergamon

Abstract We report the gas sorption ability of [Cd (μ-hmt)(μ-dca) 2] n (1)(hmt= 
hexamethylenetetramine, dca= dicyanamide), a coordination polymer with 2D rectangular 
grid structure known as the porous non-porous materials, for CO 2, CH 4, and N 2 under 
different temperatures (295 K, 195 K). It was observed that polymer adsorbs CO 2 and CH 4, 
but not N 2 even at low temperature. Also, since electron transfer behavior of 1 has an 
important role on gas adsorption, electrochemical properties of polymer and its metal ( ...