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paper41

Authors
Hossein Chiniforoshan, Nasimeh Pourrahim, Leila Tabrizi, Hossein Tavakol, Mohammad R Sabzalian, Behrouz Notash
Publication date
2014/5/24
Journal
Inorganica Chimica Acta
Volume
416
Pages
85-92
Publisher
Elsevier
Description
Abstract A series of compounds mercury (II),[Hg (CH 2 COCH 3) L] n where L= anion of 4-
NO 2 pcyd (4-nitro phenylcyanamide)(1), 4-Clpcyd (4-chloro phenylcyanamide)(2), 4-Brpcyd 
(4-bromo phenylcyanamide)(3) were synthesized from acetone and characterized by 
elemental analysis, IR, 1 H NMR, 13 C NMR and electronic absorption spectroscopies. 
Single crystal X ray analysis of 1 reveals coordination of phenylcyanamide ligand to Hg (II) 
unexpectedly occurred through amine nitrogen alone which is rare. Also the anion of ...

 

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