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Hossein Chiniforoshan, Nasimeh Pourrahim, Leila Tabrizi, Hossein Tavakol, Mohammad R Sabzalian, Behrouz Notash
Inorganica Chimica Acta
Abstract A series of compounds mercury (II),[Hg (CH 2 COCH 3) L] n where L= anion of 4-
NO 2 pcyd (4-nitro phenylcyanamide)(1), 4-Clpcyd (4-chloro phenylcyanamide)(2), 4-Brpcyd
(4-bromo phenylcyanamide)(3) were synthesized from acetone and characterized by
elemental analysis, IR, 1 H NMR, 13 C NMR and electronic absorption spectroscopies.
Single crystal X ray analysis of 1 reveals coordination of phenylcyanamide ligand to Hg (II)
unexpectedly occurred through amine nitrogen alone which is rare. Also the anion of ...