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paper43

Authors
Jamaladin Shakeri, Hassan Hadadzadeh, Hossein Tavakol
Publication date
2014/8/16
Journal
Polyhedron
Volume
78
Pages
112-122
Publisher
Pergamon
Description
Abstract The new dinuclear Re (I) complex,[ReCl (CO) 3 (μ-tptzH) Re (CO) 3], where tptzH− 
is 2, 4, 6-tri (pyridine-2-yl)-2H-1, 3, 5-triazine-1-ide has been synthesized and characterized 
by spectroscopic methods and X-ray crystallography. During the preparation of the dinuclear 
complex, a carbon atom of the triazine ring in the tptz bridging ligand is saturated by two 
consecutive redox reactions. It is worthy to mention that this partial saturation of tptz to tptzH− 
is the first example of the saturation of a triazine ring without a nucleophilic attack. The ...

 

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paper43 | Professor Hossein Tavakol

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تحت نظارت وف بومی